Tricarbonyl (1,3,5,7-cyclooctatetraene)iron

Tricarbonyl (1,3,5,7-cyclooctatetraene)iron - Names and Identifiers

Name	CYCLOOCTATETRAENE IRON TRICARBONYL
Synonyms	iron carbon monoxide cyclooctatetraene TRICARBONYLCYCLOOCTATRAENEIRON Cyclooctatetraeneirontricarbonyl Cyclooctatetraenetricarbonyliron CYCLOOCTATETRAENE IRON TRICARBONYL TRICARBONYL(CYCLOOCTATETRAENE)IRON Tricarbonyl (1,3,5,7-cyclooctatetraene)iron Iron, tricarbonyl(1,3,5,7-cyclooctatetraene)- Iron, tricarbonyl[(1,2,3,4-eta)-1,3,5,7-cyclooctatetraene]-
CAS	12093-05-9
InChI	InChI=1/C8H8.3CO.Fe/c1-2-4-6-8-7-5-3-1;3*1-2;/h1-8H;;;;/b2-1-,3-1-,4-2-,5-3-,6-4-,7-5-,8-6-,8-7-;;;

Tricarbonyl (1,3,5,7-cyclooctatetraene)iron - Physico-chemical Properties

Molecular Formula	C11H8FeO3
Molar Mass	244.02
Melting Point	93-95°C(lit.)
Boling Point	140.5°C at 760 mmHg
Flash Point	22.2°C
Water Solubility	Insoluble in water.
Vapor Presure	7.64mmHg at 25°C
Appearance	crystal
Color	red to brown
Storage Condition	2-8℃
Sensitive	Air Sensitive
MDL	MFCD00001755
Physical and Chemical Properties	Sensitivity: Air Sensitive WGK Germany:3

Tricarbonyl (1,3,5,7-cyclooctatetraene)iron - Risk and Safety

Hazard Symbols	Xn - Harmful
Risk Codes	20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
Safety Description	36 - Wear suitable protective clothing.
UN IDs	UN3466
WGK Germany	3
Hazard Class	6.1
Packing Group	II

Tricarbonyl (1,3,5,7-cyclooctatetraene)iron - Introduction

Cyclooctene iron tricarbonyl is an organometallic compound with the chemical formula Fe(C8H8)3 and a molecular weight of 358.19. It is a compound with a metal cycloalkene structure in which an iron ion forms a coordination bond with a cyclooctetraene ligand.

The properties of cyclooctetraene iron tricarbonyl include:
1. the appearance of black or blue-black solid.
2. This compound is sensitive to air and water and decomposes easily in air, so it needs to be stored and handled under an inert atmosphere.
3. With metal-metal interaction, it can form properties similar to magnetism.
4. stable structure, soluble in organic solvents such as benzene and dimethylformamide.

Use of cyclooctene iron tricarbonyl:
1. As a catalyst precursor, it is used to catalyze a variety of chemical reactions in organic synthesis.
2. for the study of organometallic chemistry and metal-metal interaction.

preparation method of cyclooctene iron tricarbonyl:
The most commonly used preparation method is through the reaction of cyclooctetraene with iron tricarbonyl. In this process, metallic iron reacts with cyclooctadiene to form the desired compound.

Safety information for cyclooctetraene iron tricarbonyl:
1. This compound is easily decomposed in the air and produces toxic substances, so it needs to be stored and handled under an inert atmosphere.
2. contact with skin and eyes may cause irritation, the operation needs to wear protective equipment, and ensure that the operation area is well ventilated.
3. Avoid inhalation, ingestion or swallowing during use, and avoid contact with oxidants and strong acids.
4. Use and handle this material in accordance with accurate safety procedures and under specialized laboratory conditions.

Last Update：2024-04-10 22:29:15